A Three-Dimensional Nickel(II) Framework from a Semi-Flexible Bipyrimidyl Ligand Showing Weak Ferromagnetic Behavior

A semi-flexible bipyrimidyl ligand, 5,5′-bipyrimidin (bpym), was used for the self-assembly of a transition metal coordination polymer, resulting in the formation of a nickel(II) compound, [Ni(Br)(2)(bpym)(2)](n) (1) with a three-dimemsional (3D) structure. Single-crystal X-ray analysis showed that...

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Detalles Bibliográficos
Autores principales: Dong, Shin-Shan, Yang, Chen-I
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401916/
https://www.ncbi.nlm.nih.gov/pubmed/30960103
http://dx.doi.org/10.3390/polym11010119
Descripción
Sumario:A semi-flexible bipyrimidyl ligand, 5,5′-bipyrimidin (bpym), was used for the self-assembly of a transition metal coordination polymer, resulting in the formation of a nickel(II) compound, [Ni(Br)(2)(bpym)(2)](n) (1) with a three-dimemsional (3D) structure. Single-crystal X-ray analysis showed that compound 1 crystallizes in the monoclinic space group C2/c and the structure represents a 3D (4,4)-connected bbe topological framework constructed of nickel(II) ions, twisted cis-μ-bpym and planar trans-μ-bpym groups. Magnetic characterization revealed that 1 shows antiferromagnetic coupling between the pyrimidyl-bridged Ni(II) ions along with weak ferromagnetism due to spin canting with a magnetic ordering below T(c) = 3.4 K.

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