Effect of Thermal Ageing on the Impact and Flexural Damage Behaviour of Carbon Fibre-Reinforced Epoxy Laminates

Most of the composite materials that are used in aerospace structures have been manufactured using a thermostable matrix, as epoxy resin. The region of stability of these polymers is defined by the glass transition temperature (T(g)). However, operating temperatures close and above the T(g) can cause a variation in the properties of the polymer and consequently, modify the mechanical properties of the composite material. Therefore, it is necessary to understand the failure mechanisms that occur in the material in order to ensure stability and durability. The effect of temperature and time of exposure on the impact and flexural mechanical responses of carbon/epoxy composites are studied in this work. For that purpose, ageing treatments at temperatures below and above the T(g) have been considered and then, impact and flexural tests have been performed. It was observed that thermal ageing cause two different effects: at temperatures below the T(g), there is an increase of the maximum strength because of a post-curing effect; however, the mechanical properties decrease at higher temperatures of thermal ageing due to the thermo-oxidation of the epoxy resin and the loss of adhesion in the matrix/fibre interface.