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The Importance of Solvent Effects on the Mechanism of the Pfeiffer Effect

The Pfeiffer effect is observed when an optically active compound such as an amino acid is introduced to a solution containing a labile racemic metal complex, and an equilibrium shift is obtained. The “perturbation” results in an excess of one enantiomer over the other. The shift is a result of a pr...

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Detalles Bibliográficos
Autores principales: Lunkley, Jamie L., Nguyen, Ngoc M., Tuminaro, Kristina M., Margittai, Dana, Muller, Gilles
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6402352/
https://www.ncbi.nlm.nih.gov/pubmed/30854379
http://dx.doi.org/10.3390/inorganics6030087