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Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells

The formation of defects at surfaces and grain boundaries (GBs) during the fabrication of solution‐processed perovskite film are thought to be responsible for its instability. Herein, Eu‐porphyrin complex (Eu‐pyP) is directly doped into methylammonium lead triiodide (MAPbI(3)) precursor, perfectly f...

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Autores principales: Feng, Xiaoxia, Chen, Ruihao, Nan, Zi‐Ang, Lv, Xudong, Meng, Ruiqian, Cao, Jing, Tang, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6402397/
https://www.ncbi.nlm.nih.gov/pubmed/30886810
http://dx.doi.org/10.1002/advs.201802040
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author Feng, Xiaoxia
Chen, Ruihao
Nan, Zi‐Ang
Lv, Xudong
Meng, Ruiqian
Cao, Jing
Tang, Yu
author_facet Feng, Xiaoxia
Chen, Ruihao
Nan, Zi‐Ang
Lv, Xudong
Meng, Ruiqian
Cao, Jing
Tang, Yu
author_sort Feng, Xiaoxia
collection PubMed
description The formation of defects at surfaces and grain boundaries (GBs) during the fabrication of solution‐processed perovskite film are thought to be responsible for its instability. Herein, Eu‐porphyrin complex (Eu‐pyP) is directly doped into methylammonium lead triiodide (MAPbI(3)) precursor, perfectly fabricating 2D (Eu‐pyP)(0.5)MA(n) (‐1)Pb(n)I(3) (n) (+1) platelets inlaying the GBs of 3D polycrystalline interstices in this protocol. The device based on Eu‐pyP doped perovskite film possesses a champion efficiency of 18.2%. More importantly, the doped perovskite solar cells device shows beyond 85% retention of its pristine efficiency value, whereas the pure MAPbI(3) device has a rapid drop in efficiency down to 10% within 100 h under 45% humidity at 85 °C in AM 1.5 G. The above acquired perovskite films reveal an unpredictable thermodynamic self‐healing ability. Consequently, the findings provide an avenue for defect passivation to synchronously improve resistibility to moisture, heat, and solar light including UV.
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spelling pubmed-64023972019-03-18 Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells Feng, Xiaoxia Chen, Ruihao Nan, Zi‐Ang Lv, Xudong Meng, Ruiqian Cao, Jing Tang, Yu Adv Sci (Weinh) Communications The formation of defects at surfaces and grain boundaries (GBs) during the fabrication of solution‐processed perovskite film are thought to be responsible for its instability. Herein, Eu‐porphyrin complex (Eu‐pyP) is directly doped into methylammonium lead triiodide (MAPbI(3)) precursor, perfectly fabricating 2D (Eu‐pyP)(0.5)MA(n) (‐1)Pb(n)I(3) (n) (+1) platelets inlaying the GBs of 3D polycrystalline interstices in this protocol. The device based on Eu‐pyP doped perovskite film possesses a champion efficiency of 18.2%. More importantly, the doped perovskite solar cells device shows beyond 85% retention of its pristine efficiency value, whereas the pure MAPbI(3) device has a rapid drop in efficiency down to 10% within 100 h under 45% humidity at 85 °C in AM 1.5 G. The above acquired perovskite films reveal an unpredictable thermodynamic self‐healing ability. Consequently, the findings provide an avenue for defect passivation to synchronously improve resistibility to moisture, heat, and solar light including UV. John Wiley and Sons Inc. 2019-01-21 /pmc/articles/PMC6402397/ /pubmed/30886810 http://dx.doi.org/10.1002/advs.201802040 Text en © 2019 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Feng, Xiaoxia
Chen, Ruihao
Nan, Zi‐Ang
Lv, Xudong
Meng, Ruiqian
Cao, Jing
Tang, Yu
Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells
title Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells
title_full Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells
title_fullStr Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells
title_full_unstemmed Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells
title_short Perfection of Perovskite Grain Boundary Passivation by Eu‐Porphyrin Complex for Overall‐Stable Perovskite Solar Cells
title_sort perfection of perovskite grain boundary passivation by eu‐porphyrin complex for overall‐stable perovskite solar cells
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6402397/
https://www.ncbi.nlm.nih.gov/pubmed/30886810
http://dx.doi.org/10.1002/advs.201802040
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