Metal(II) Coordination Polymers Derived from Mixed 4-Imidazole Ligands and Carboxylates: Syntheses, Topological Structures, and Properties

Four new metal–organic coordination polymers [Cu(L)(mpa)]·3H(2)O (1), [Co(L)(mpa)]·H(2)O (2), [Zn(L)(mpa)]·H(2)O (3), and [Cd(L)(mpa)(H(2)O)]·H(2)O (4) were synthesized by reactions of the corresponding metal(II) salts based on mixed ligands of 1,4-di(1H-imidazol-4-yl)benzene (L) and 4-methylphthalic acid (H(2)mpa), respectively. The structures of the complexes were characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction. Compound 1 exhibits a binodal 4-connected three dimensional (3D) architecture with (6(5)·8)-CdSO(4) topology, while complexes 2 and 3 are isostructural and have two-dimensional (2D) layer structure with (4, 4) sql topology based on the binuclear metal subunits. Complex 4 has the same 2D layer structure with (4, 4) sql topology as complexes 2 and 3, but the inclined interpenetration of parallel sets of layers result in the formation with 2D + 2D → 3D framework. The activated sample 1 shows selective CO(2) uptake over N(2). The photoluminiscent properties together with quantum yield (QY) and luminescence lifetime are also investigated for complexes 3 and 4 in the solid state at room temperature.