Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)

In this study, poly(3,4-ethylenedioxythiophene), a benchmark-conducting polymer, was doped by protons. The doping and de-doping processes, using protonic acid and a base, were fully reversible. We predicted possible doping sites along the polymer chain using density functional theory (DFT) calculati...

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Autores principales: He, Shuzhong, Mukaida, Masakazu, Kirihara, Kazuhiro, Lyu, Lingyun, Wei, Qingshuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404222/
https://www.ncbi.nlm.nih.gov/pubmed/30960990
http://dx.doi.org/10.3390/polym10101065
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author He, Shuzhong
Mukaida, Masakazu
Kirihara, Kazuhiro
Lyu, Lingyun
Wei, Qingshuo
author_facet He, Shuzhong
Mukaida, Masakazu
Kirihara, Kazuhiro
Lyu, Lingyun
Wei, Qingshuo
author_sort He, Shuzhong
collection PubMed
description In this study, poly(3,4-ethylenedioxythiophene), a benchmark-conducting polymer, was doped by protons. The doping and de-doping processes, using protonic acid and a base, were fully reversible. We predicted possible doping sites along the polymer chain using density functional theory (DFT) calculations. This study sheds potential light and understanding on the molecular design of highly conductive organic materials.
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spelling pubmed-64042222019-04-02 Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene) He, Shuzhong Mukaida, Masakazu Kirihara, Kazuhiro Lyu, Lingyun Wei, Qingshuo Polymers (Basel) Article In this study, poly(3,4-ethylenedioxythiophene), a benchmark-conducting polymer, was doped by protons. The doping and de-doping processes, using protonic acid and a base, were fully reversible. We predicted possible doping sites along the polymer chain using density functional theory (DFT) calculations. This study sheds potential light and understanding on the molecular design of highly conductive organic materials. MDPI 2018-09-25 /pmc/articles/PMC6404222/ /pubmed/30960990 http://dx.doi.org/10.3390/polym10101065 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
He, Shuzhong
Mukaida, Masakazu
Kirihara, Kazuhiro
Lyu, Lingyun
Wei, Qingshuo
Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)
title Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)
title_full Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)
title_fullStr Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)
title_full_unstemmed Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)
title_short Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)
title_sort reversible protonic doping in poly(3,4-ethylenedioxythiophene)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404222/
https://www.ncbi.nlm.nih.gov/pubmed/30960990
http://dx.doi.org/10.3390/polym10101065
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AT lyulingyun reversibleprotonicdopinginpoly34ethylenedioxythiophene
AT weiqingshuo reversibleprotonicdopinginpoly34ethylenedioxythiophene

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