Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives

Dirhodium(II) complex-catalyzed [3 + 2] reactions between N-arylaminocyclopropanes and alkyne derivatives are described. The cycloaddition products proved to be versatile synthetic intermediates. trans-Cyclic β-amino acids and derivatives thereof can be conveniently synthesized using this cycloaddit...

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Detalles Bibliográficos
Autores principales: Liu, Wentong, Kuang, Yi, Wang, Zhifan, Zhu, Jin, Wang, Yuanhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404392/
https://www.ncbi.nlm.nih.gov/pubmed/30873238
http://dx.doi.org/10.3762/bjoc.15.48
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author Liu, Wentong
Kuang, Yi
Wang, Zhifan
Zhu, Jin
Wang, Yuanhua
author_facet Liu, Wentong
Kuang, Yi
Wang, Zhifan
Zhu, Jin
Wang, Yuanhua
author_sort Liu, Wentong
collection PubMed
description Dirhodium(II) complex-catalyzed [3 + 2] reactions between N-arylaminocyclopropanes and alkyne derivatives are described. The cycloaddition products proved to be versatile synthetic intermediates. trans-Cyclic β-amino acids and derivatives thereof can be conveniently synthesized using this cycloaddition protocol.
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spelling pubmed-64043922019-03-14 Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives Liu, Wentong Kuang, Yi Wang, Zhifan Zhu, Jin Wang, Yuanhua Beilstein J Org Chem Full Research Paper Dirhodium(II) complex-catalyzed [3 + 2] reactions between N-arylaminocyclopropanes and alkyne derivatives are described. The cycloaddition products proved to be versatile synthetic intermediates. trans-Cyclic β-amino acids and derivatives thereof can be conveniently synthesized using this cycloaddition protocol. Beilstein-Institut 2019-02-25 /pmc/articles/PMC6404392/ /pubmed/30873238 http://dx.doi.org/10.3762/bjoc.15.48 Text en Copyright © 2019, Liu et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Liu, Wentong
Kuang, Yi
Wang, Zhifan
Zhu, Jin
Wang, Yuanhua
Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives
title Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives
title_full Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives
title_fullStr Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives
title_full_unstemmed Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives
title_short Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives
title_sort dirhodium(ii)-catalyzed [3 + 2] cycloaddition of n-arylaminocyclopropane with alkyne derivatives
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404392/
https://www.ncbi.nlm.nih.gov/pubmed/30873238
http://dx.doi.org/10.3762/bjoc.15.48
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