LCST phase behavior of benzo-21-crown-7 with different alkyl chains

The introduction of hydrophobic units into crown ethers can dramatically decrease the critical transition temperature of LCST and realize macroscopic phase separation at low to moderate temperature and concentration. Minor modifications in the chemical structure of crown ethers (benzo-21-crown-7, B2...

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Detalles Bibliográficos
Autores principales: Deng, Yan, Li, Xing, Zhang, Qiao, Luo, Zheng, Han, Chengyou, Dong, Shengyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404474/
https://www.ncbi.nlm.nih.gov/pubmed/30873228
http://dx.doi.org/10.3762/bjoc.15.38
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author Deng, Yan
Li, Xing
Zhang, Qiao
Luo, Zheng
Han, Chengyou
Dong, Shengyi
author_facet Deng, Yan
Li, Xing
Zhang, Qiao
Luo, Zheng
Han, Chengyou
Dong, Shengyi
author_sort Deng, Yan
collection PubMed
description The introduction of hydrophobic units into crown ethers can dramatically decrease the critical transition temperature of LCST and realize macroscopic phase separation at low to moderate temperature and concentration. Minor modifications in the chemical structure of crown ethers (benzo-21-crown-7, B21C7s) can effectively control the thermo-responsive properties.
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spelling pubmed-64044742019-03-14 LCST phase behavior of benzo-21-crown-7 with different alkyl chains Deng, Yan Li, Xing Zhang, Qiao Luo, Zheng Han, Chengyou Dong, Shengyi Beilstein J Org Chem Letter The introduction of hydrophobic units into crown ethers can dramatically decrease the critical transition temperature of LCST and realize macroscopic phase separation at low to moderate temperature and concentration. Minor modifications in the chemical structure of crown ethers (benzo-21-crown-7, B21C7s) can effectively control the thermo-responsive properties. Beilstein-Institut 2019-02-14 /pmc/articles/PMC6404474/ /pubmed/30873228 http://dx.doi.org/10.3762/bjoc.15.38 Text en Copyright © 2019, Deng et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Deng, Yan
Li, Xing
Zhang, Qiao
Luo, Zheng
Han, Chengyou
Dong, Shengyi
LCST phase behavior of benzo-21-crown-7 with different alkyl chains
title LCST phase behavior of benzo-21-crown-7 with different alkyl chains
title_full LCST phase behavior of benzo-21-crown-7 with different alkyl chains
title_fullStr LCST phase behavior of benzo-21-crown-7 with different alkyl chains
title_full_unstemmed LCST phase behavior of benzo-21-crown-7 with different alkyl chains
title_short LCST phase behavior of benzo-21-crown-7 with different alkyl chains
title_sort lcst phase behavior of benzo-21-crown-7 with different alkyl chains
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404474/
https://www.ncbi.nlm.nih.gov/pubmed/30873228
http://dx.doi.org/10.3762/bjoc.15.38
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