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Di- and Tetrairon(III) μ-Oxido Complexes of an N3S-Donor Ligand: Catalyst Precursors for Alkene Oxidations

The new di- and tetranuclear Fe(III) μ-oxido complexes [Fe(4)(μ-O)(4)(PTEBIA)(4)](CF(3)SO(3))(4)(CH(3)CN)(2)] (1a), [Fe(2)(μ-O)Cl(2)(PTEBIA)(2)](CF(3)SO(3))(2) (1b), and [Fe(2)(μ-O)(HCOO)(2)(PTEBIA)(2)](ClO(4))(2) (MeOH) (2) were prepared from the sulfur-containing ligand (2-((2,4-dimethylphenyl)thi...

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Detalles Bibliográficos
Autores principales: Das, Biswanath, Al-Hunaiti, Afnan, Sánchez-Eguía, Brenda N., Zeglio, Erica, Demeshko, Serhiy, Dechert, Sebastian, Braunger, Steffen, Haukka, Matti, Repo, Timo, Castillo, Ivan, Nordlander, Ebbe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6405480/
https://www.ncbi.nlm.nih.gov/pubmed/30881952
http://dx.doi.org/10.3389/fchem.2019.00097