In-Situ Fabrication of g-C(3)N(4)/ZnO Nanocomposites for Photocatalytic Degradation of Methylene Blue: Synthesis Procedure Does Matter

The nanocomposite preparation procedure plays an important role in achieving a well-established heterostructured junction, and hence, an optimized photocatalytic activity. In this study, a series of g-C(3)N(4)/ZnO nanocomposites were prepared through two distinct procedures of a low-cost, environmentally-friendly, in-situ fabrication process, with urea and zinc acetate being the only precursor materials. The physicochemical properties of synthesized g-C(3)N(4)/ZnO composites were mainly characterized by XRD, UV–VIS diffuse reflectance spectroscopy (DRS), N(2) adsorption-desorption, FTIR, TEM, and SEM. These nanocomposites’ photocatalytic properties were evaluated in methylene blue (MB) dye photodecomposition under UV and sunlight irradiation. Interestingly, compared with ZnO nanorods, g-C(3)N(4)/ZnO nanocomposites (x:1, obtained from urea and ZnO nanorods) exhibited weak photocatalytic activity likely due to a “shading effect”, while nanocomposites (x:1 CN, made from g-C(3)N(4) and zinc acetate) showed enhanced photocatalytic activity that can be ascribed to the effective establishment of heterojunctions. A kinetics study showed that a maximum reaction rate constant of 0.1862 min(-1) can be achieved under solar light illumination, which is two times higher than that of bare ZnO nanorods. The photocatalytic mechanism was revealed by determining reactive species through adding a series of scavengers. It suggested that reactive ●O(2)(−) and h(+) radicals played a major role in promoting dye photodegradation.