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The Role of Catalyst Support, Diluent and Co-Catalyst in Chromium-Mediated Heterogeneous Ethylene Trimerisation
Sequential treatment of a previously-calcined solid oxide support (i.e. SiO(2), γ-Al(2)O(3), or mixed SiO(2)–Al(2)O(3)) with solutions of Cr{N(SiMe(3))(2)}(3) (0.71 wt% Cr) and a Lewis acidic alkyl aluminium-based co-catalyst (15 molar equivalents) affords initiator systems active for the oligomeris...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer US
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6413812/ https://www.ncbi.nlm.nih.gov/pubmed/30956506 http://dx.doi.org/10.1007/s11244-018-0891-8 |