Dioxygen insertion into the gold(i)–hydride bond: spin orbit coupling effects in the spotlight for oxidative addition

O(2) insertion into a Au(i)–H bond occurs through an oxidative addition/recombination mechanism, showing peculiar differences with respect to Pd(ii)–H, for which O(2) insertion takes place through a hydrogen abstraction mechanism in the triplet potential energy surface with a pure spin transition st...

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Detalles Bibliográficos
Autores principales: Gaggioli, Carlo Alberto, Belpassi, Leonardo, Tarantelli, Francesco, Zuccaccia, Daniele, Harvey, Jeremy N., Belanzoni, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6413884/
https://www.ncbi.nlm.nih.gov/pubmed/30996862
http://dx.doi.org/10.1039/c6sc02161a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6413884/
https://www.ncbi.nlm.nih.gov/pubmed/30996862
http://dx.doi.org/10.1039/c6sc02161a

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