Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN

Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl(2)) loading was as low as 1/64 equivalent to c...

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Detalles Bibliográficos
Autores principales: Hu, Xin, Cui, Guopeng, Zhu, Ning, Zhai, Jinglin, Guo, Kai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415051/
https://www.ncbi.nlm.nih.gov/pubmed/30966103
http://dx.doi.org/10.3390/polym10010068
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author Hu, Xin
Cui, Guopeng
Zhu, Ning
Zhai, Jinglin
Guo, Kai
author_facet Hu, Xin
Cui, Guopeng
Zhu, Ning
Zhai, Jinglin
Guo, Kai
author_sort Hu, Xin
collection PubMed
description Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl(2)) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me(6)-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by “off-on” impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.
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spelling pubmed-64150512019-04-02 Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN Hu, Xin Cui, Guopeng Zhu, Ning Zhai, Jinglin Guo, Kai Polymers (Basel) Article Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl(2)) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me(6)-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by “off-on” impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP. MDPI 2018-01-13 /pmc/articles/PMC6415051/ /pubmed/30966103 http://dx.doi.org/10.3390/polym10010068 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Hu, Xin
Cui, Guopeng
Zhu, Ning
Zhai, Jinglin
Guo, Kai
Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN
title Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN
title_full Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN
title_fullStr Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN
title_full_unstemmed Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN
title_short Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN
title_sort photoinduced cu(ii)-mediated rdrp to p(vdf-co-ctfe)-g-pan
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415051/
https://www.ncbi.nlm.nih.gov/pubmed/30966103
http://dx.doi.org/10.3390/polym10010068
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