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Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing
We developed a simple analytical model to describe the instantaneous location and angle of rod-like conductive fillers as a function of cell growth during the foaming of conductive polymer composites (CPCs). First, we modelled the motion of the fillers that resulted from the growth of one cell. Then...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415160/ https://www.ncbi.nlm.nih.gov/pubmed/30966296 http://dx.doi.org/10.3390/polym10030261 |
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author | Wang, Sai Ameli, Amir Shaayegan, Vahid Kazemi, Yasamin Huang, Yifeng Naguib, Hani E. Park, Chul B. |
author_facet | Wang, Sai Ameli, Amir Shaayegan, Vahid Kazemi, Yasamin Huang, Yifeng Naguib, Hani E. Park, Chul B. |
author_sort | Wang, Sai |
collection | PubMed |
description | We developed a simple analytical model to describe the instantaneous location and angle of rod-like conductive fillers as a function of cell growth during the foaming of conductive polymer composites (CPCs). First, we modelled the motion of the fillers that resulted from the growth of one cell. Then, by taking into account the fillers located at the line that connected the centres of the two growing cells, we found the final filler’s angle and location. We identified this as a function of the corresponding cell size, filler size, and the filler’s initial angle and location. We based the model’s development on the assumption that a polymer melt is incompressible during cell growth. The two-cell growth model is better than the one-cell growth model because it describes the filler’s movement in the cell wall between the two growing cells. The results revealed that the fillers near the cell were the ones most affected by the cell growth, while those at the midpoint between the two cells were the least affected. As a cell grows, its affected polymer area also increases. A dimensionless factor η was introduced to demonstrate the effects of the cell size and the filler length on the filler’s interconnectivity in the CPC foams. It is vital to keep the filler length comparable to the cell size when preparing CPC foams with the desired electrical conductivity. Our research provides a deeper understanding of the mechanism through which foaming influences the filler connections in CPC foams. |
format | Online Article Text |
id | pubmed-6415160 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-64151602019-04-02 Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing Wang, Sai Ameli, Amir Shaayegan, Vahid Kazemi, Yasamin Huang, Yifeng Naguib, Hani E. Park, Chul B. Polymers (Basel) Article We developed a simple analytical model to describe the instantaneous location and angle of rod-like conductive fillers as a function of cell growth during the foaming of conductive polymer composites (CPCs). First, we modelled the motion of the fillers that resulted from the growth of one cell. Then, by taking into account the fillers located at the line that connected the centres of the two growing cells, we found the final filler’s angle and location. We identified this as a function of the corresponding cell size, filler size, and the filler’s initial angle and location. We based the model’s development on the assumption that a polymer melt is incompressible during cell growth. The two-cell growth model is better than the one-cell growth model because it describes the filler’s movement in the cell wall between the two growing cells. The results revealed that the fillers near the cell were the ones most affected by the cell growth, while those at the midpoint between the two cells were the least affected. As a cell grows, its affected polymer area also increases. A dimensionless factor η was introduced to demonstrate the effects of the cell size and the filler length on the filler’s interconnectivity in the CPC foams. It is vital to keep the filler length comparable to the cell size when preparing CPC foams with the desired electrical conductivity. Our research provides a deeper understanding of the mechanism through which foaming influences the filler connections in CPC foams. MDPI 2018-03-02 /pmc/articles/PMC6415160/ /pubmed/30966296 http://dx.doi.org/10.3390/polym10030261 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Wang, Sai Ameli, Amir Shaayegan, Vahid Kazemi, Yasamin Huang, Yifeng Naguib, Hani E. Park, Chul B. Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing |
title | Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing |
title_full | Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing |
title_fullStr | Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing |
title_full_unstemmed | Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing |
title_short | Modelling of Rod-Like Fillers’ Rotation and Translation near Two Growing Cells in Conductive Polymer Composite Foam Processing |
title_sort | modelling of rod-like fillers’ rotation and translation near two growing cells in conductive polymer composite foam processing |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415160/ https://www.ncbi.nlm.nih.gov/pubmed/30966296 http://dx.doi.org/10.3390/polym10030261 |
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