Mg(II) Coordination Polymers Based on Flexible Isomeric Tetracarboxylate Ligands: Syntheses, Structures, Structural Transformation and Luminescent Properties

By using a new flexible tetracarboxylic acid, bis(3,5-dicarboxyphenyl) adipoamide, H(4)L(1), and its isomer, bis(2,5-dicarboxyphenyl)adipoamide, H(4)L(2), three Mg(II) coordination polymers, {[Mg(2)(L(1))(H(2)O)(2)]·2EtOH·3H(2)O}(n), 1, [Mg(2)(L(1))(H(2)O)(8)](n), 2, and {[Mg(2)(L(2))(H(2)O)(6)]·H(2)O}(n), 3, have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Complexes 1 and 2 are the solvent ratio-dependent hydrothermally stable products. The tetracarboxylate ligand of complex 1 connects eight Mg(II) ions through nine oxygen atoms, resulting in a three-dimensional (3D) 5-connected uninodal net with a rare non-interpenetrating (4(4).6(6))-pcu-5-Pmna topology, whereas those of 2 and 3 link four Mg(II) ions through four oxygen atoms and six Mg(II) ions through six oxygen atoms, forming a 1D linear chain and a 3,6-connected 2-nodal 3D net having {4.6(2)}(2){4(2).6(10).8(3)}-rtl topology, respectively. Complex 1 shows a series of structural transformations on heating to 200 °C and almost reversible structural transformation when the activated products were immersed in a mixture of ethanol and water or on hydrothermal. Likewise, complex 2 exhibits a reversible structural transformation on heating/hydrothermal, while 3 exhibits irreversible structural transformations. All three complexes exhibit blue light emissions, with that of complex 3 being much more intense.