Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit

[Image: see text] Synthesis of a number of disiloxane containing cyclo- and bicyclooligosilanes is described starting from the dipotassium 1,5-oligosiloxanylene diide derived from 1,3-bis[tris(trimethylsilyl)silyl]tetramethyldisiloxane. In addition, the use of this particular fragment as ligand for...

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Autores principales: Zitz, Rainer, Baumgartner, Judith, Marschner, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415795/
https://www.ncbi.nlm.nih.gov/pubmed/30880866
http://dx.doi.org/10.1021/acs.organomet.9b00013
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author Zitz, Rainer
Baumgartner, Judith
Marschner, Christoph
author_facet Zitz, Rainer
Baumgartner, Judith
Marschner, Christoph
author_sort Zitz, Rainer
collection PubMed
description [Image: see text] Synthesis of a number of disiloxane containing cyclo- and bicyclooligosilanes is described starting from the dipotassium 1,5-oligosiloxanylene diide derived from 1,3-bis[tris(trimethylsilyl)silyl]tetramethyldisiloxane. In addition, the use of this particular fragment as ligand for zinc and group 4 metallocene complexes was studied. Both types of compounds exhibit marked structural differences compared to related compounds containing Si-Si-Si units instead of the Si-O-Si fragment.
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spelling pubmed-64157952019-03-14 Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit Zitz, Rainer Baumgartner, Judith Marschner, Christoph Organometallics [Image: see text] Synthesis of a number of disiloxane containing cyclo- and bicyclooligosilanes is described starting from the dipotassium 1,5-oligosiloxanylene diide derived from 1,3-bis[tris(trimethylsilyl)silyl]tetramethyldisiloxane. In addition, the use of this particular fragment as ligand for zinc and group 4 metallocene complexes was studied. Both types of compounds exhibit marked structural differences compared to related compounds containing Si-Si-Si units instead of the Si-O-Si fragment. American Chemical Society 2019-02-28 2019-03-11 /pmc/articles/PMC6415795/ /pubmed/30880866 http://dx.doi.org/10.1021/acs.organomet.9b00013 Text en Copyright © 2019 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Zitz, Rainer
Baumgartner, Judith
Marschner, Christoph
Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit
title Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit
title_full Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit
title_fullStr Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit
title_full_unstemmed Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit
title_short Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit
title_sort chemistry of a 1,5-oligosilanylene dianion containing a disiloxane unit
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415795/
https://www.ncbi.nlm.nih.gov/pubmed/30880866
http://dx.doi.org/10.1021/acs.organomet.9b00013
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