MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization

MgCl(2)-supported titanium Ziegler-Natta catalyst containing CO(2)-based poly(propylene ether carbonate) diols as a potential internal electron donor (IED) was synthesized and employed for 1-butene polymerization. When compared with the Ziegler-Natta catalyst using poly(polypropylene glycol) as IED,...

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Detalles Bibliográficos
Autores principales: Cui, Xiaopeng, Bai, Qing, Ma, Kai, Yang, Min, Liu, Binyuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418720/
https://www.ncbi.nlm.nih.gov/pubmed/30965930
http://dx.doi.org/10.3390/polym9110627
Descripción
Sumario:MgCl(2)-supported titanium Ziegler-Natta catalyst containing CO(2)-based poly(propylene ether carbonate) diols as a potential internal electron donor (IED) was synthesized and employed for 1-butene polymerization. When compared with the Ziegler-Natta catalyst using poly(polypropylene glycol) as IED, the catalyst prepared with poly(propylene ether carbonate) diols showed good particle morphology, higher activity and stereoselectivity. The results suggested that existence of the carbonate group within the structure of poly(propylene ether carbonate) diols truly plays an important role in improving the performance of the catalyst for the 1-butene polymerization.

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