MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization

MgCl(2)-supported titanium Ziegler-Natta catalyst containing CO(2)-based poly(propylene ether carbonate) diols as a potential internal electron donor (IED) was synthesized and employed for 1-butene polymerization. When compared with the Ziegler-Natta catalyst using poly(polypropylene glycol) as IED,...

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Detalles Bibliográficos
Autores principales: Cui, Xiaopeng, Bai, Qing, Ma, Kai, Yang, Min, Liu, Binyuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418720/
https://www.ncbi.nlm.nih.gov/pubmed/30965930
http://dx.doi.org/10.3390/polym9110627
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author Cui, Xiaopeng
Bai, Qing
Ma, Kai
Yang, Min
Liu, Binyuan
author_facet Cui, Xiaopeng
Bai, Qing
Ma, Kai
Yang, Min
Liu, Binyuan
author_sort Cui, Xiaopeng
collection PubMed
description MgCl(2)-supported titanium Ziegler-Natta catalyst containing CO(2)-based poly(propylene ether carbonate) diols as a potential internal electron donor (IED) was synthesized and employed for 1-butene polymerization. When compared with the Ziegler-Natta catalyst using poly(polypropylene glycol) as IED, the catalyst prepared with poly(propylene ether carbonate) diols showed good particle morphology, higher activity and stereoselectivity. The results suggested that existence of the carbonate group within the structure of poly(propylene ether carbonate) diols truly plays an important role in improving the performance of the catalyst for the 1-butene polymerization.
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spelling pubmed-64187202019-04-02 MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization Cui, Xiaopeng Bai, Qing Ma, Kai Yang, Min Liu, Binyuan Polymers (Basel) Article MgCl(2)-supported titanium Ziegler-Natta catalyst containing CO(2)-based poly(propylene ether carbonate) diols as a potential internal electron donor (IED) was synthesized and employed for 1-butene polymerization. When compared with the Ziegler-Natta catalyst using poly(polypropylene glycol) as IED, the catalyst prepared with poly(propylene ether carbonate) diols showed good particle morphology, higher activity and stereoselectivity. The results suggested that existence of the carbonate group within the structure of poly(propylene ether carbonate) diols truly plays an important role in improving the performance of the catalyst for the 1-butene polymerization. MDPI 2017-11-17 /pmc/articles/PMC6418720/ /pubmed/30965930 http://dx.doi.org/10.3390/polym9110627 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Cui, Xiaopeng
Bai, Qing
Ma, Kai
Yang, Min
Liu, Binyuan
MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization
title MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization
title_full MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization
title_fullStr MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization
title_full_unstemmed MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization
title_short MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization
title_sort mgcl(2)-supported titanium ziegler-natta catalyst using carbon dioxide-based poly(propylene ether carbonate) diols as internal electron donor for 1-butene polymerization
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418720/
https://www.ncbi.nlm.nih.gov/pubmed/30965930
http://dx.doi.org/10.3390/polym9110627
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