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Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex

A series of new fluorenylamido-ligated zirconium complexes bearing an electron-donating adamantyl group on the amido ligand were synthesized and characterized by elemental analysis, (1)H NMR, and single crystal X-ray analysis. The coordination mode of the fluorenyl ligand to the zirconium metal was...

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Detalles Bibliográficos
Autores principales: Sun, Yanjie, Li, Shuhui, Shiono, Takeshi, Cai, Zhengguo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418878/
https://www.ncbi.nlm.nih.gov/pubmed/30965933
http://dx.doi.org/10.3390/polym9110632