Synthesis and Properties of a Novel Environmental Epoxidized Glycidyl Ester of Ricinoleic Acetic Ester Plasticizer for Poly(vinyl chloride)

A novel renewable plasticizer based on castor oil, epoxidized glycidyl ester of ricinoleic acetic ester (EGERAE), was synthesized and applied into Poly(vinyl chloride) (PVC) for the first time. Its molecular structure was characterized by FT-IR and (1)H NMR. The effects of replacement of petroleum-b...

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Detalles Bibliográficos
Autores principales: Chen, Jie, Li, Ke, Wang, Yigang, Huang, Jinrui, Nie, Xiaoan, Jiang, Jianchun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418936/
https://www.ncbi.nlm.nih.gov/pubmed/30965956
http://dx.doi.org/10.3390/polym9120640
Descripción
Sumario:A novel renewable plasticizer based on castor oil, epoxidized glycidyl ester of ricinoleic acetic ester (EGERAE), was synthesized and applied into Poly(vinyl chloride) (PVC) for the first time. Its molecular structure was characterized by FT-IR and (1)H NMR. The effects of replacement of petroleum-based commercial plasticizer dioctyl phthalate (DOP) with EGERAE in poly(vinyl chloride) (PVC) films were researched. Thermal stability, dynamic mechanical property and mechanical properties of PVC films were investigated with thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and tensile tests. The results indicated that this castor oil-based plasticizer was able to improve the thermal stability of PVC blends when partially of completely substituting for DOP. Furthermore, EGERAE endowed PVC resin with enhanced flexibility. In addition, the exudation, volatility and extraction resistance characteristics of plasticizers were researched. The degradation mechanism and possible interaction between EGERAE and PVC molecules in the plasticized system were also investigated.