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Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine
We report on the use of different reaction conditions, e.g., temperature, time, and/or concentration of reactants, to gain control over the particle formation of a bioinspired coordination polymer based on copper(II) and adenine, allowing homogeneous particle production from micro- to submicro-, and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418955/ https://www.ncbi.nlm.nih.gov/pubmed/30965869 http://dx.doi.org/10.3390/polym9110565 |
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author | Vegas, Verónica G. Villar-Alonso, Marta Gómez-García, Carlos J. Zamora, Félix Amo-Ochoa, Pilar |
author_facet | Vegas, Verónica G. Villar-Alonso, Marta Gómez-García, Carlos J. Zamora, Félix Amo-Ochoa, Pilar |
author_sort | Vegas, Verónica G. |
collection | PubMed |
description | We report on the use of different reaction conditions, e.g., temperature, time, and/or concentration of reactants, to gain control over the particle formation of a bioinspired coordination polymer based on copper(II) and adenine, allowing homogeneous particle production from micro- to submicro-, and up to nano-size. Additionally, studies on this reaction carried out in the presence of different surfactants gives rise to the control of the particle size due to the modulation of the electrostatic interactions. Stability of the water suspensions obtained within the time and pH has been evaluated. We have also studied that there is no significant effect of the size reduction in the magnetic properties of the Cu(II)-adenine coordination polymer. |
format | Online Article Text |
id | pubmed-6418955 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-64189552019-04-02 Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine Vegas, Verónica G. Villar-Alonso, Marta Gómez-García, Carlos J. Zamora, Félix Amo-Ochoa, Pilar Polymers (Basel) Article We report on the use of different reaction conditions, e.g., temperature, time, and/or concentration of reactants, to gain control over the particle formation of a bioinspired coordination polymer based on copper(II) and adenine, allowing homogeneous particle production from micro- to submicro-, and up to nano-size. Additionally, studies on this reaction carried out in the presence of different surfactants gives rise to the control of the particle size due to the modulation of the electrostatic interactions. Stability of the water suspensions obtained within the time and pH has been evaluated. We have also studied that there is no significant effect of the size reduction in the magnetic properties of the Cu(II)-adenine coordination polymer. MDPI 2017-11-01 /pmc/articles/PMC6418955/ /pubmed/30965869 http://dx.doi.org/10.3390/polym9110565 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Vegas, Verónica G. Villar-Alonso, Marta Gómez-García, Carlos J. Zamora, Félix Amo-Ochoa, Pilar Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine |
title | Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine |
title_full | Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine |
title_fullStr | Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine |
title_full_unstemmed | Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine |
title_short | Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine |
title_sort | direct formation of sub-micron and nanoparticles of a bioinspired coordination polymer based on copper with adenine |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418955/ https://www.ncbi.nlm.nih.gov/pubmed/30965869 http://dx.doi.org/10.3390/polym9110565 |
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