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Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine

We report on the use of different reaction conditions, e.g., temperature, time, and/or concentration of reactants, to gain control over the particle formation of a bioinspired coordination polymer based on copper(II) and adenine, allowing homogeneous particle production from micro- to submicro-, and...

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Detalles Bibliográficos
Autores principales: Vegas, Verónica G., Villar-Alonso, Marta, Gómez-García, Carlos J., Zamora, Félix, Amo-Ochoa, Pilar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418955/
https://www.ncbi.nlm.nih.gov/pubmed/30965869
http://dx.doi.org/10.3390/polym9110565
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author Vegas, Verónica G.
Villar-Alonso, Marta
Gómez-García, Carlos J.
Zamora, Félix
Amo-Ochoa, Pilar
author_facet Vegas, Verónica G.
Villar-Alonso, Marta
Gómez-García, Carlos J.
Zamora, Félix
Amo-Ochoa, Pilar
author_sort Vegas, Verónica G.
collection PubMed
description We report on the use of different reaction conditions, e.g., temperature, time, and/or concentration of reactants, to gain control over the particle formation of a bioinspired coordination polymer based on copper(II) and adenine, allowing homogeneous particle production from micro- to submicro-, and up to nano-size. Additionally, studies on this reaction carried out in the presence of different surfactants gives rise to the control of the particle size due to the modulation of the electrostatic interactions. Stability of the water suspensions obtained within the time and pH has been evaluated. We have also studied that there is no significant effect of the size reduction in the magnetic properties of the Cu(II)-adenine coordination polymer.
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spelling pubmed-64189552019-04-02 Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine Vegas, Verónica G. Villar-Alonso, Marta Gómez-García, Carlos J. Zamora, Félix Amo-Ochoa, Pilar Polymers (Basel) Article We report on the use of different reaction conditions, e.g., temperature, time, and/or concentration of reactants, to gain control over the particle formation of a bioinspired coordination polymer based on copper(II) and adenine, allowing homogeneous particle production from micro- to submicro-, and up to nano-size. Additionally, studies on this reaction carried out in the presence of different surfactants gives rise to the control of the particle size due to the modulation of the electrostatic interactions. Stability of the water suspensions obtained within the time and pH has been evaluated. We have also studied that there is no significant effect of the size reduction in the magnetic properties of the Cu(II)-adenine coordination polymer. MDPI 2017-11-01 /pmc/articles/PMC6418955/ /pubmed/30965869 http://dx.doi.org/10.3390/polym9110565 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Vegas, Verónica G.
Villar-Alonso, Marta
Gómez-García, Carlos J.
Zamora, Félix
Amo-Ochoa, Pilar
Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine
title Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine
title_full Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine
title_fullStr Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine
title_full_unstemmed Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine
title_short Direct Formation of Sub-Micron and Nanoparticles of a Bioinspired Coordination Polymer Based on Copper with Adenine
title_sort direct formation of sub-micron and nanoparticles of a bioinspired coordination polymer based on copper with adenine
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418955/
https://www.ncbi.nlm.nih.gov/pubmed/30965869
http://dx.doi.org/10.3390/polym9110565
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