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Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes
A series of novel chiral nonmetallocene pincer-type rare-earth metal dialkyl complexes bearing the chiral monoanionic tridentate C(2)-symmetric 1,3-bis(oxazolinymethylidene)isoindoline (BOXMI-H) ligand (BOXMI)Ln(CH(2)SiMe(3))(2) 1–3 (1: Ln = Sc, yield = 57%; 2: Ln = Lu, yield = 55%; 3: Ln = Y, yield...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419008/ https://www.ncbi.nlm.nih.gov/pubmed/30965837 http://dx.doi.org/10.3390/polym9100531 |