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Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes

A series of novel chiral nonmetallocene pincer-type rare-earth metal dialkyl complexes bearing the chiral monoanionic tridentate C(2)-symmetric 1,3-bis(oxazolinymethylidene)isoindoline (BOXMI-H) ligand (BOXMI)Ln(CH(2)SiMe(3))(2) 1–3 (1: Ln = Sc, yield = 57%; 2: Ln = Lu, yield = 55%; 3: Ln = Y, yield...

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Detalles Bibliográficos
Autores principales: Yu, Chao, Zhou, Dahai, Yan, Xiangqian, Gao, Fei, Zhang, Li, Zhang, Shaowen, Li, Xiaofang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419008/
https://www.ncbi.nlm.nih.gov/pubmed/30965837
http://dx.doi.org/10.3390/polym9100531

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