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Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends

We have recently solved the tumbling-snake model for concentrated polymer solutions and entangled melts in the academic case of a monodisperse sample. Here, we extend these studies and provide the stationary solutions of the tumbling-snake model both analytically, for small shear rates, and via Brow...

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Detalles Bibliográficos
Autores principales: Stephanou, Pavlos S., Kröger, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419188/
https://www.ncbi.nlm.nih.gov/pubmed/30960360
http://dx.doi.org/10.3390/polym11020376
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author Stephanou, Pavlos S.
Kröger, Martin
author_facet Stephanou, Pavlos S.
Kröger, Martin
author_sort Stephanou, Pavlos S.
collection PubMed
description We have recently solved the tumbling-snake model for concentrated polymer solutions and entangled melts in the academic case of a monodisperse sample. Here, we extend these studies and provide the stationary solutions of the tumbling-snake model both analytically, for small shear rates, and via Brownian dynamics simulations, for a bidisperse sample over a wide range of shear rates and model parameters. We further show that the tumbling-snake model bears the necessary capacity to compare well with available linear and non-linear rheological data for bidisperse systems. This capacity is added to the already documented ability of the model to accurately predict the shear rheology of monodisperse systems.
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spelling pubmed-64191882019-04-02 Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends Stephanou, Pavlos S. Kröger, Martin Polymers (Basel) Article We have recently solved the tumbling-snake model for concentrated polymer solutions and entangled melts in the academic case of a monodisperse sample. Here, we extend these studies and provide the stationary solutions of the tumbling-snake model both analytically, for small shear rates, and via Brownian dynamics simulations, for a bidisperse sample over a wide range of shear rates and model parameters. We further show that the tumbling-snake model bears the necessary capacity to compare well with available linear and non-linear rheological data for bidisperse systems. This capacity is added to the already documented ability of the model to accurately predict the shear rheology of monodisperse systems. MDPI 2019-02-20 /pmc/articles/PMC6419188/ /pubmed/30960360 http://dx.doi.org/10.3390/polym11020376 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Stephanou, Pavlos S.
Kröger, Martin
Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends
title Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends
title_full Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends
title_fullStr Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends
title_full_unstemmed Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends
title_short Assessment of the Tumbling-Snake Model against Linear and Nonlinear Rheological Data of Bidisperse Polymer Blends
title_sort assessment of the tumbling-snake model against linear and nonlinear rheological data of bidisperse polymer blends
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419188/
https://www.ncbi.nlm.nih.gov/pubmed/30960360
http://dx.doi.org/10.3390/polym11020376
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