Comparative Study on Kinetics of Ethylene and Propylene Polymerizations with Supported Ziegler–Natta Catalyst: Catalyst Fragmentation Promoted by Polymer Crystalline Lamellae

The kinetic behaviors of ethylene and propylene polymerizations with the same MgCl(2)-supported Ziegler–Natta (Z–N) catalyst containing an internal electron donor were compared. Changes of polymerization activity and active center concentration ([C*]) with time in the first 10 min were determined. A...

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Detalles Bibliográficos
Autores principales: Zhang, Zhen, Jiang, Baiyu, He, Feng, Fu, Zhisheng, Xu, Junting, Fan, Zhiqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419229/
https://www.ncbi.nlm.nih.gov/pubmed/30960342
http://dx.doi.org/10.3390/polym11020358

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419229/
https://www.ncbi.nlm.nih.gov/pubmed/30960342
http://dx.doi.org/10.3390/polym11020358

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