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Comparative Study on Kinetics of Ethylene and Propylene Polymerizations with Supported Ziegler–Natta Catalyst: Catalyst Fragmentation Promoted by Polymer Crystalline Lamellae
The kinetic behaviors of ethylene and propylene polymerizations with the same MgCl(2)-supported Ziegler–Natta (Z–N) catalyst containing an internal electron donor were compared. Changes of polymerization activity and active center concentration ([C*]) with time in the first 10 min were determined. A...
Autores principales: | Zhang, Zhen, Jiang, Baiyu, He, Feng, Fu, Zhisheng, Xu, Junting, Fan, Zhiqiang |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419229/ https://www.ncbi.nlm.nih.gov/pubmed/30960342 http://dx.doi.org/10.3390/polym11020358 |
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