Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution

Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–S bond in a highly straightforward and efficient manner. Various enamines and (hetero)aryl thiols could be transformed smoothly under undivided electrolytic cell conditions. Moreover, this electrosynthesis strateg...

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Detalles Bibliográficos
Autores principales: Li, Dandan, Li, Shuaibing, Peng, Chong, Lu, Lijun, Wang, Shengchun, Wang, Pan, Chen, Yi-Hung, Cong, Hengjiang, Lei, Aiwen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419947/
https://www.ncbi.nlm.nih.gov/pubmed/30996999
http://dx.doi.org/10.1039/c8sc05143g
Descripción
Sumario:Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–S bond in a highly straightforward and efficient manner. Various enamines and (hetero)aryl thiols could be transformed smoothly under undivided electrolytic cell conditions. Moreover, this electrosynthesis strategy not only avoided the use of chemical oxidants and transition metal catalysts, but also exhibited excellent atom economy.

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