Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution

Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–S bond in a highly straightforward and efficient manner. Various enamines and (hetero)aryl thiols could be transformed smoothly under undivided electrolytic cell conditions. Moreover, this electrosynthesis strateg...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Dandan, Li, Shuaibing, Peng, Chong, Lu, Lijun, Wang, Shengchun, Wang, Pan, Chen, Yi-Hung, Cong, Hengjiang, Lei, Aiwen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419947/
https://www.ncbi.nlm.nih.gov/pubmed/30996999
http://dx.doi.org/10.1039/c8sc05143g
_version_ 1783404032178520064
author Li, Dandan
Li, Shuaibing
Peng, Chong
Lu, Lijun
Wang, Shengchun
Wang, Pan
Chen, Yi-Hung
Cong, Hengjiang
Lei, Aiwen
author_facet Li, Dandan
Li, Shuaibing
Peng, Chong
Lu, Lijun
Wang, Shengchun
Wang, Pan
Chen, Yi-Hung
Cong, Hengjiang
Lei, Aiwen
author_sort Li, Dandan
collection PubMed
description Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–S bond in a highly straightforward and efficient manner. Various enamines and (hetero)aryl thiols could be transformed smoothly under undivided electrolytic cell conditions. Moreover, this electrosynthesis strategy not only avoided the use of chemical oxidants and transition metal catalysts, but also exhibited excellent atom economy.
format Online
Article
Text
id pubmed-6419947
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-64199472019-04-17 Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution Li, Dandan Li, Shuaibing Peng, Chong Lu, Lijun Wang, Shengchun Wang, Pan Chen, Yi-Hung Cong, Hengjiang Lei, Aiwen Chem Sci Chemistry Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–S bond in a highly straightforward and efficient manner. Various enamines and (hetero)aryl thiols could be transformed smoothly under undivided electrolytic cell conditions. Moreover, this electrosynthesis strategy not only avoided the use of chemical oxidants and transition metal catalysts, but also exhibited excellent atom economy. Royal Society of Chemistry 2019-01-18 /pmc/articles/PMC6419947/ /pubmed/30996999 http://dx.doi.org/10.1039/c8sc05143g Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Li, Dandan
Li, Shuaibing
Peng, Chong
Lu, Lijun
Wang, Shengchun
Wang, Pan
Chen, Yi-Hung
Cong, Hengjiang
Lei, Aiwen
Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution
title Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution
title_full Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution
title_fullStr Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution
title_full_unstemmed Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution
title_short Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H(2) evolution
title_sort electrochemical oxidative c–h/s–h cross-coupling between enamines and thiophenols with h(2) evolution
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419947/
https://www.ncbi.nlm.nih.gov/pubmed/30996999
http://dx.doi.org/10.1039/c8sc05143g
work_keys_str_mv AT lidandan electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT lishuaibing electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT pengchong electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT lulijun electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT wangshengchun electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT wangpan electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT chenyihung electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT conghengjiang electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution
AT leiaiwen electrochemicaloxidativechshcrosscouplingbetweenenaminesandthiophenolswithh2evolution

Ejemplares similares