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Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives

Acenes have received a lot of attention because of their inherent and tunable absorbing, emissive, and charge transport properties for electronic, photovoltaic, and singlet fission applications, among others. Such properties are directly governed by molecular packing, and therefore, controlling thei...

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Autores principales: Gozalvez, Cristian, Zafra, Jose L., Saeki, Akinori, Melle-Franco, Manuel, Casado, Juan, Mateo-Alonso, Aurelio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419948/
https://www.ncbi.nlm.nih.gov/pubmed/30996992
http://dx.doi.org/10.1039/c8sc04845b
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author Gozalvez, Cristian
Zafra, Jose L.
Saeki, Akinori
Melle-Franco, Manuel
Casado, Juan
Mateo-Alonso, Aurelio
author_facet Gozalvez, Cristian
Zafra, Jose L.
Saeki, Akinori
Melle-Franco, Manuel
Casado, Juan
Mateo-Alonso, Aurelio
author_sort Gozalvez, Cristian
collection PubMed
description Acenes have received a lot of attention because of their inherent and tunable absorbing, emissive, and charge transport properties for electronic, photovoltaic, and singlet fission applications, among others. Such properties are directly governed by molecular packing, and therefore, controlling their arrangement in the solid state is of utmost importance in order to increase their performance. Herein, we describe a new solid-state ordering strategy that allows obtaining 1D mixed π-stacks of acene and azaacene derivatives. In addition, we illustrate that charge transport can be modulated by the electronic nature of the encapsulated phenazine, opening new perspectives in the design, preparation and development of supramolecular organic semiconductors.
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spelling pubmed-64199482019-04-17 Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives Gozalvez, Cristian Zafra, Jose L. Saeki, Akinori Melle-Franco, Manuel Casado, Juan Mateo-Alonso, Aurelio Chem Sci Chemistry Acenes have received a lot of attention because of their inherent and tunable absorbing, emissive, and charge transport properties for electronic, photovoltaic, and singlet fission applications, among others. Such properties are directly governed by molecular packing, and therefore, controlling their arrangement in the solid state is of utmost importance in order to increase their performance. Herein, we describe a new solid-state ordering strategy that allows obtaining 1D mixed π-stacks of acene and azaacene derivatives. In addition, we illustrate that charge transport can be modulated by the electronic nature of the encapsulated phenazine, opening new perspectives in the design, preparation and development of supramolecular organic semiconductors. Royal Society of Chemistry 2019-01-09 /pmc/articles/PMC6419948/ /pubmed/30996992 http://dx.doi.org/10.1039/c8sc04845b Text en This journal is © The Royal Society of Chemistry 2019 https://creativecommons.org/licenses/by-nc/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Gozalvez, Cristian
Zafra, Jose L.
Saeki, Akinori
Melle-Franco, Manuel
Casado, Juan
Mateo-Alonso, Aurelio
Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
title Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
title_full Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
title_fullStr Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
title_full_unstemmed Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
title_short Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
title_sort charge transport modulation in pseudorotaxane 1d stacks of acene and azaacene derivatives
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419948/
https://www.ncbi.nlm.nih.gov/pubmed/30996992
http://dx.doi.org/10.1039/c8sc04845b
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