Selective benzylic C–H monooxygenation mediated by iodine oxides

A method for the selective monooxdiation of secondary benzylic C–H bonds is described using an N-oxyl catalyst and a hypervalent iodine species as a terminal oxidant. Combinations of ammonium iodate and catalytic N-hydroxyphthalimide (NHPI) were shown to be effective in the selective oxidation of n-...

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Detalles Bibliográficos
Autores principales: LaMartina, Kelsey B, Kuck, Haley K, Oglesbee, Linda S, Al-Odaini, Asma, Boaz, Nicholas C
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6423598/
https://www.ncbi.nlm.nih.gov/pubmed/30931001
http://dx.doi.org/10.3762/bjoc.15.55

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6423598/
https://www.ncbi.nlm.nih.gov/pubmed/30931001
http://dx.doi.org/10.3762/bjoc.15.55

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