Plasma Exfoliated Graphene: Preparation via Rapid, Mild Thermal Reduction of Graphene Oxide and Application in Lithium Batteries

A simple, novel approach is proposed for the preparation of plasma-exfoliated graphene (PEGN) by reducing graphene oxide (GO) through a dielectric-barrier discharge (DBD) plasma treatment in a H(2) atmosphere. The surface chemistry, microstructures, and crystallinity of the prepared samples were characterized via X-ray photoelectron spectroscopy, transmission electron microscopy, and Raman spectrometry to determine the formation mechanism of the PEGN. The results demonstrated that the prepared PEGN had only a few layers in its structure and that most of the functional groups containing oxygen on the GO surface were removed. The PEGN exhibited a considerably higher capacity, better cycling stability, and favorable electron transfer rate for use as a cathode material for lithium-ion batteries. This proposed approach is fast, convenient, and inexpensive, constituting a novel means of producing graphene.