Surface Modification of Carbon Fibers by Grafting PEEK-NH2 for Improving Interfacial Adhesion with Polyetheretherketone

Due to the non-polar nature and low wettability of carbon fibers (CFs), the interfacial adhesion between CFs and the polyetheretherketone (PEEK) matrix is poor, and this has negative effects on the mechanical properties of CF/PEEK composites. In this work, we established a modification method to improve the interface between CFs and PEEK based chemical grafting of aminated polyetheretherketone (PEEK-NH(2)) on CFs to create an interfacial layer which has competency with the PEEK matrix. The changed chemical composition, surface morphology, surface energy, and interlaminar shear strength were investigated. After grafting, the interlaminar shear strength (ILSS) was improved by 33.4% due to the covalent bonds in the interface region, as well as having good compatibility between the interface modifier and PEEK. Finally, Dynamic Mechanical Analysis (DMA) and Scanning Electron Microscopy (SEM) observation also confirmed that the properties of the modified CF/PEEK composites interface were enhanced. This work is, therefore, a beneficial approach towards enhancing the mechanical properties of thermoplastic composites by controlling the interface between CFs and the PEEK matrix.