Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis

Reactions of three magnesium(i) dimers, [{((Ar)Nacnac)Mg–}(2)] ((Ar)Nacnac = [(ArNCMe)(2)CH](–); Ar = xylyl (Xyl), mesityl (Mes) or 2,6-diethylphenyl (Dep)), with either 1,1-diphenylethylene (DPE), α-methylstyrene (MS), trans-stilbene (TS) or diphenylacetylene (DPA) led to the 1,2-addition of the Mg...

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Detalles Bibliográficos
Autores principales: Dange, Deepak, Gair, Andrew R., Jones, Dafydd D. L., Juckel, Martin, Aldridge, Simon, Jones, Cameron
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6428033/
https://www.ncbi.nlm.nih.gov/pubmed/30996903
http://dx.doi.org/10.1039/c9sc00200f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6428033/
https://www.ncbi.nlm.nih.gov/pubmed/30996903
http://dx.doi.org/10.1039/c9sc00200f

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