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Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis
Reactions of three magnesium(i) dimers, [{((Ar)Nacnac)Mg–}(2)] ((Ar)Nacnac = [(ArNCMe)(2)CH](–); Ar = xylyl (Xyl), mesityl (Mes) or 2,6-diethylphenyl (Dep)), with either 1,1-diphenylethylene (DPE), α-methylstyrene (MS), trans-stilbene (TS) or diphenylacetylene (DPA) led to the 1,2-addition of the Mg...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6428033/ https://www.ncbi.nlm.nih.gov/pubmed/30996903 http://dx.doi.org/10.1039/c9sc00200f |