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Dinuclear manganese alkoxide complexes as catalysts for C–N bond cleavage of simple tertiary N,N-dialkylamides to give esters

Amide bonds are stable due to the resonance between the nitrogen lone pair and the carbonyl moiety, and therefore the chemical transformation of amides, especially tertiary amides, involving C–N bond fission is considered one of the most difficult organic reactions, unavoidably requiring harsh react...

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Detalles Bibliográficos
Autores principales: Nagae, Haruki, Hirai, Takahiro, Kato, Daiki, Soma, Shusei, Akebi, Shin-ya, Mashima, Kazushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429592/
https://www.ncbi.nlm.nih.gov/pubmed/30996863
http://dx.doi.org/10.1039/c8sc05819a

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