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A rational quest for selectivity through precise ligand-positioning in tandem DNA-catalysed Friedel–Crafts alkylation/asymmetric protonation

Covalent anchorage of a metallic co-factor to a DNA-based architecture is merely the only way to ensure an accurate positioning of a catalytic site within the chiral micro-environment offered by the DNA double helix. Ultimately, it also allows a fine-tuning of the catalytic pocket through simple syn...

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Detalles Bibliográficos
Autores principales:	Mansot, Justine, Aubert, Sidonie, Duchemin, Nicolas, Vasseur, Jean-Jacques, Arseniyadis, Stellios, Smietana, Michael
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429601/ https://www.ncbi.nlm.nih.gov/pubmed/30996865 http://dx.doi.org/10.1039/c8sc05543b

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