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Tuning the formal potential of ferrocyanide over a 2.1 V range

We report the synthesis and characterization of homoleptic borane adducts of hexacyanoferrate(ii). Borane coordination blueshifts d–d transitions and CN IR and Raman frequencies. Control over redox properties is established with respect to borane Lewis acidity, reflected in peak anodic potential shi...

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Detalles Bibliográficos
Autores principales:	McNicholas, Brendon J., Grubbs, Robert H., Winkler, Jay R., Gray, Harry B., Despagnet-Ayoub, Emmanuelle
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6430091/ https://www.ncbi.nlm.nih.gov/pubmed/30996955 http://dx.doi.org/10.1039/c8sc04972f

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