Cargando…
Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp(3))–H functionalization mediated by organophotoredox and chiral chromium hybrid catalysis
We describe a hybrid system that realizes cooperativity between an organophotoredox acridinium catalyst and a chiral chromium complex catalyst, thereby enabling unprecedented exploitation of unactivated hydrocarbon alkenes as precursors to chiral allylchromium nucleophiles for asymmetric allylation...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6430092/ https://www.ncbi.nlm.nih.gov/pubmed/30996935 http://dx.doi.org/10.1039/c8sc05677c |