Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling

Synthesis of a new phosphene-free nano-size formamidine-based palladium complex have been achieved. The molecular structure of novel palladium complex have been confirmed using spectroscopic methods of analysis as well as physical characterizations. The synthesized complex has been used as a catalys...

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Autores principales: Khormi, Afaf Y., Farghaly, Thoraya. A., Shaaban, Mohamed R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431754/
https://www.ncbi.nlm.nih.gov/pubmed/30957046
http://dx.doi.org/10.1016/j.heliyon.2019.e01367
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author Khormi, Afaf Y.
Farghaly, Thoraya. A.
Shaaban, Mohamed R.
author_facet Khormi, Afaf Y.
Farghaly, Thoraya. A.
Shaaban, Mohamed R.
author_sort Khormi, Afaf Y.
collection PubMed
description Synthesis of a new phosphene-free nano-size formamidine-based palladium complex have been achieved. The molecular structure of novel palladium complex have been confirmed using spectroscopic methods of analysis as well as physical characterizations. The synthesized complex has been used as a catalyst for microwave assisted aqueous Suzuki-Miyaura Cross-coupling (SMC) of aryl bromides with phenylboronic acid. The formamidine-based Pd(II)-complex exhibited excellent catalytic activity to obtain biaryls using mild reaction conditions.
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spelling pubmed-64317542019-04-05 Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling Khormi, Afaf Y. Farghaly, Thoraya. A. Shaaban, Mohamed R. Heliyon Article Synthesis of a new phosphene-free nano-size formamidine-based palladium complex have been achieved. The molecular structure of novel palladium complex have been confirmed using spectroscopic methods of analysis as well as physical characterizations. The synthesized complex has been used as a catalyst for microwave assisted aqueous Suzuki-Miyaura Cross-coupling (SMC) of aryl bromides with phenylboronic acid. The formamidine-based Pd(II)-complex exhibited excellent catalytic activity to obtain biaryls using mild reaction conditions. Elsevier 2019-03-20 /pmc/articles/PMC6431754/ /pubmed/30957046 http://dx.doi.org/10.1016/j.heliyon.2019.e01367 Text en © 2019 The Authors http://creativecommons.org/licenses/by/4.0/ This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Khormi, Afaf Y.
Farghaly, Thoraya. A.
Shaaban, Mohamed R.
Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling
title Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling
title_full Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling
title_fullStr Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling
title_full_unstemmed Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling
title_short Pyrimidyl formamidine palladium(II) complex as a nanocatalyst for aqueous Suzuki-Miyaura coupling
title_sort pyrimidyl formamidine palladium(ii) complex as a nanocatalyst for aqueous suzuki-miyaura coupling
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431754/
https://www.ncbi.nlm.nih.gov/pubmed/30957046
http://dx.doi.org/10.1016/j.heliyon.2019.e01367
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