Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)

The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exch...

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Autores principales: López-Cabrelles, Javier, Mínguez Espallargas, Guillermo, Coronado, Eugenio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431858/
https://www.ncbi.nlm.nih.gov/pubmed/30979261
http://dx.doi.org/10.3390/polym8050171
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author López-Cabrelles, Javier
Mínguez Espallargas, Guillermo
Coronado, Eugenio
author_facet López-Cabrelles, Javier
Mínguez Espallargas, Guillermo
Coronado, Eugenio
author_sort López-Cabrelles, Javier
collection PubMed
description The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl(4)](−). This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.
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spelling pubmed-64318582019-04-02 Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−) López-Cabrelles, Javier Mínguez Espallargas, Guillermo Coronado, Eugenio Polymers (Basel) Article The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl(4)](−). This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework. MDPI 2016-04-26 /pmc/articles/PMC6431858/ /pubmed/30979261 http://dx.doi.org/10.3390/polym8050171 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
López-Cabrelles, Javier
Mínguez Espallargas, Guillermo
Coronado, Eugenio
Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)
title Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)
title_full Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)
title_fullStr Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)
title_full_unstemmed Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)
title_short Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)
title_sort single-crystal-to-single-crystal anion exchange in a gadolinium mof: incorporation of poms and [aucl(4)](−)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431858/
https://www.ncbi.nlm.nih.gov/pubmed/30979261
http://dx.doi.org/10.3390/polym8050171
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