Preparation of Microporous Polypropylene/Titanium Dioxide Composite Membranes with Enhanced Electrolyte Uptake Capability via Melt Extruding and Stretching

In this work, a blending strategy based on compounding the hydrophilic titanium dioxide (TiO(2)) particles with the host polypropylene (PP) pellets, followed by the common membrane manufacture process of melt extruding/annealing/stretching, was used to improve the polarity and thus electrolyte uptake capability of the PP-based microporous membranes. The influence of the TiO(2) particles on the crystallinity and crystalline orientation of the PP matrix was studied using differential scanning calorimetry (DSC), X-ray diffraction (XRD), and infrared dichroic methods. The results showed that the TiO(2) incorporation has little influence on the oriented lamellar structure of the PP-based composite films. Investigations of the deformation behavior indicated that both the lamellar separation and interfacial debonding occurred when the PP/TiO(2) composite films were subjected to uniaxial tensile stress. The scanning electron microscopy (SEM) observations verified that two forms of micropores were generated in the stretched PP/TiO(2) composite membranes. Compared to the virgin PP membrane, the PP/TiO(2) composite membranes especially at high TiO(2) loadings showed significant improvements in terms of water vapor permeability, polarity, and electrolyte uptake capability. The electrolyte uptake of the PP/TiO(2) composite membrane with 40 wt % TiO(2) was 104%, which had almost doubled compared with that of the virgin PP membrane.