Cargando…
SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light
The present study highlights the facile synthesis of polyaniline (PANI)-based nanocomposites doped with SrTiO(3) nanocubes synthesized via the in situ oxidative polymerization technique using ammonium persulfate (APS) as an oxidant in acidic medium for the photocatalytic degradation of methylene blu...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432585/ https://www.ncbi.nlm.nih.gov/pubmed/30979143 http://dx.doi.org/10.3390/polym8020027 |
_version_ | 1783406169317965824 |
---|---|
author | Shahabuddin, Syed Muhamad Sarih, Norazilawati Mohamad, Sharifah Joon Ching, Juan |
author_facet | Shahabuddin, Syed Muhamad Sarih, Norazilawati Mohamad, Sharifah Joon Ching, Juan |
author_sort | Shahabuddin, Syed |
collection | PubMed |
description | The present study highlights the facile synthesis of polyaniline (PANI)-based nanocomposites doped with SrTiO(3) nanocubes synthesized via the in situ oxidative polymerization technique using ammonium persulfate (APS) as an oxidant in acidic medium for the photocatalytic degradation of methylene blue dye. Field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), UV–Vis spectroscopy, Brunauer–Emmett–Teller analysis (BET) and Fourier transform infrared spectroscopy (FTIR) measurements were used to characterize the prepared nanocomposite photocatalysts. The photocatalytic efficiencies of the photocatalysts were examined by degrading methylene blue (MB) under visible light irradiation. The results showed that the degradation efficiency of the composite photocatalysts that were doped with SrTiO(3) nanocubes was higher than that of the undoped polyaniline. In this study, the effects of the weight ratio of polyaniline to SrTiO(3) on the photocatalytic activities were investigated. The results revealed that the nanocomposite P-Sr500 was found to be an optimum photocatalyst, with a 97% degradation efficiency after 90 min of irradiation under solar light. |
format | Online Article Text |
id | pubmed-6432585 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-64325852019-04-02 SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light Shahabuddin, Syed Muhamad Sarih, Norazilawati Mohamad, Sharifah Joon Ching, Juan Polymers (Basel) Article The present study highlights the facile synthesis of polyaniline (PANI)-based nanocomposites doped with SrTiO(3) nanocubes synthesized via the in situ oxidative polymerization technique using ammonium persulfate (APS) as an oxidant in acidic medium for the photocatalytic degradation of methylene blue dye. Field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), UV–Vis spectroscopy, Brunauer–Emmett–Teller analysis (BET) and Fourier transform infrared spectroscopy (FTIR) measurements were used to characterize the prepared nanocomposite photocatalysts. The photocatalytic efficiencies of the photocatalysts were examined by degrading methylene blue (MB) under visible light irradiation. The results showed that the degradation efficiency of the composite photocatalysts that were doped with SrTiO(3) nanocubes was higher than that of the undoped polyaniline. In this study, the effects of the weight ratio of polyaniline to SrTiO(3) on the photocatalytic activities were investigated. The results revealed that the nanocomposite P-Sr500 was found to be an optimum photocatalyst, with a 97% degradation efficiency after 90 min of irradiation under solar light. MDPI 2016-02-15 /pmc/articles/PMC6432585/ /pubmed/30979143 http://dx.doi.org/10.3390/polym8020027 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Shahabuddin, Syed Muhamad Sarih, Norazilawati Mohamad, Sharifah Joon Ching, Juan SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light |
title | SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light |
title_full | SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light |
title_fullStr | SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light |
title_full_unstemmed | SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light |
title_short | SrTiO(3) Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light |
title_sort | srtio(3) nanocube-doped polyaniline nanocomposites with enhanced photocatalytic degradation of methylene blue under visible light |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432585/ https://www.ncbi.nlm.nih.gov/pubmed/30979143 http://dx.doi.org/10.3390/polym8020027 |
work_keys_str_mv | AT shahabuddinsyed srtio3nanocubedopedpolyanilinenanocompositeswithenhancedphotocatalyticdegradationofmethyleneblueundervisiblelight AT muhamadsarihnorazilawati srtio3nanocubedopedpolyanilinenanocompositeswithenhancedphotocatalyticdegradationofmethyleneblueundervisiblelight AT mohamadsharifah srtio3nanocubedopedpolyanilinenanocompositeswithenhancedphotocatalyticdegradationofmethyleneblueundervisiblelight AT joonchingjuan srtio3nanocubedopedpolyanilinenanocompositeswithenhancedphotocatalyticdegradationofmethyleneblueundervisiblelight |