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Investigations of the Ligand Electronic Effects on α-Diimine Nickel(II) Catalyzed Ethylene Polymerization

The synthesis and characterization of a series of dibenzhydryl-based α-diimine Ni(II) complexes bearing a range of electron-donating or -withdrawing groups are described. Polymerization with ethylene is investigated in detail, involving the activator effect, influence of polymerization conditions on...

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Detalles Bibliográficos
Autores principales: Guo, Lihua, Dai, Shengyu, Chen, Changle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432586/
https://www.ncbi.nlm.nih.gov/pubmed/30979131
http://dx.doi.org/10.3390/polym8020037