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Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer

Acyl(chloro)phosphines RC(O)P(Cl)(t-Bu) have been prepared by formal insertion of tert-butyl phosphinidene (t-Bu–P) from t-BuPA (A = C(14)H(10) or anthracene) into the C–Cl bond of acyl chlorides. We show that the under-explored acyl(chloro)phosphine functional group provides an efficient method to...

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Detalles Bibliográficos
Autores principales:	Szkop, Kevin M., Geeson, Michael B., Stephan, Douglas W., Cummins, Christopher C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432624/ https://www.ncbi.nlm.nih.gov/pubmed/30996956 http://dx.doi.org/10.1039/c8sc05657a

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