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Rewritable Optical Patterns in Light-Responsive Ultrahigh Molecular Weight Polyethylene
[Image: see text] Spiropyran is used as a photochromic dye to create colored patterns in highly drawn ultrahigh molecular weight polyethylene (UHMW PE) films. The dye is incorporated in highly crystalline, drawn UHMW PE tapes and fibers and isomerizes to its merocyanine state upon UV light irradiati...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6433162/ https://www.ncbi.nlm.nih.gov/pubmed/30923798 http://dx.doi.org/10.1021/acsapm.8b00117 |
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author | Lafleur, Sarah S. D. Severn, John R. Verpaalen, Rob C. P. Schenning, Albert P. H. J. Bastiaansen, Cees W. M. |
author_facet | Lafleur, Sarah S. D. Severn, John R. Verpaalen, Rob C. P. Schenning, Albert P. H. J. Bastiaansen, Cees W. M. |
author_sort | Lafleur, Sarah S. D. |
collection | PubMed |
description | [Image: see text] Spiropyran is used as a photochromic dye to create colored patterns in highly drawn ultrahigh molecular weight polyethylene (UHMW PE) films. The dye is incorporated in highly crystalline, drawn UHMW PE tapes and fibers and isomerizes to its merocyanine state upon UV light irradiation, resulting in a color change from transparent to purple. The isomerization from merocyanine to spiropyran to erase the color can be simply induced by using heat or a green LED light. The combination of the use of a mask and the reversibility of the isomerization results in colored patterns that can be written, erased, and rewritten using UV light and heat or green LED light. |
format | Online Article Text |
id | pubmed-6433162 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American
Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-64331622019-03-26 Rewritable Optical Patterns in Light-Responsive Ultrahigh Molecular Weight Polyethylene Lafleur, Sarah S. D. Severn, John R. Verpaalen, Rob C. P. Schenning, Albert P. H. J. Bastiaansen, Cees W. M. ACS Appl Polym Mater [Image: see text] Spiropyran is used as a photochromic dye to create colored patterns in highly drawn ultrahigh molecular weight polyethylene (UHMW PE) films. The dye is incorporated in highly crystalline, drawn UHMW PE tapes and fibers and isomerizes to its merocyanine state upon UV light irradiation, resulting in a color change from transparent to purple. The isomerization from merocyanine to spiropyran to erase the color can be simply induced by using heat or a green LED light. The combination of the use of a mask and the reversibility of the isomerization results in colored patterns that can be written, erased, and rewritten using UV light and heat or green LED light. American Chemical Society 2019-01-31 2019-03-08 /pmc/articles/PMC6433162/ /pubmed/30923798 http://dx.doi.org/10.1021/acsapm.8b00117 Text en Copyright © 2019 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. |
spellingShingle | Lafleur, Sarah S. D. Severn, John R. Verpaalen, Rob C. P. Schenning, Albert P. H. J. Bastiaansen, Cees W. M. Rewritable Optical Patterns in Light-Responsive Ultrahigh Molecular Weight Polyethylene |
title | Rewritable Optical Patterns in Light-Responsive Ultrahigh
Molecular Weight Polyethylene |
title_full | Rewritable Optical Patterns in Light-Responsive Ultrahigh
Molecular Weight Polyethylene |
title_fullStr | Rewritable Optical Patterns in Light-Responsive Ultrahigh
Molecular Weight Polyethylene |
title_full_unstemmed | Rewritable Optical Patterns in Light-Responsive Ultrahigh
Molecular Weight Polyethylene |
title_short | Rewritable Optical Patterns in Light-Responsive Ultrahigh
Molecular Weight Polyethylene |
title_sort | rewritable optical patterns in light-responsive ultrahigh
molecular weight polyethylene |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6433162/ https://www.ncbi.nlm.nih.gov/pubmed/30923798 http://dx.doi.org/10.1021/acsapm.8b00117 |
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