Cargando…

Large-scale structure formation in ionic solution and its role in electrolysis and conductivity

That water may not be an inert medium was indicated by the presence at water’s interfaces a negatively charged solute free zone of several hundred microns in thickness called the exclusion zone (EZ). Further evidence was demonstrated by Ovchinnikova’s experiments (2009) showing that water can store...

Descripción completa

Detalles Bibliográficos
Autores principales: Yee, Chut-Ngeow, Ooi, C. H. Raymond, Tan, Luck-Pheng, Misran, Misni, Tang, Nyiak-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6435176/
https://www.ncbi.nlm.nih.gov/pubmed/30913207
http://dx.doi.org/10.1371/journal.pone.0213697
_version_ 1783406606642315264
author Yee, Chut-Ngeow
Ooi, C. H. Raymond
Tan, Luck-Pheng
Misran, Misni
Tang, Nyiak-Tao
author_facet Yee, Chut-Ngeow
Ooi, C. H. Raymond
Tan, Luck-Pheng
Misran, Misni
Tang, Nyiak-Tao
author_sort Yee, Chut-Ngeow
collection PubMed
description That water may not be an inert medium was indicated by the presence at water’s interfaces a negatively charged solute free zone of several hundred microns in thickness called the exclusion zone (EZ). Further evidence was demonstrated by Ovchinnikova’s experiments (2009) showing that water can store and release substantial amount of charge. We demonstrate that the charge storage capacity of water arises from highly stable large-scale ionic structures with measurable charge imbalances and discrete levels of charge density. We also show evidence that the charge zones formation requires ionic solutes, and their formation correlate to large change in conductivity, by as much as 250%. Our experiments indicate that large-scale structuring plays a pivotal role in electrolysis and conductivity in ionic solution. We propose that water is an electrochemically active medium and present a new model of electrolysis and conductivity in ionic solution.
format Online
Article
Text
id pubmed-6435176
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher Public Library of Science
record_format MEDLINE/PubMed
spelling pubmed-64351762019-04-08 Large-scale structure formation in ionic solution and its role in electrolysis and conductivity Yee, Chut-Ngeow Ooi, C. H. Raymond Tan, Luck-Pheng Misran, Misni Tang, Nyiak-Tao PLoS One Research Article That water may not be an inert medium was indicated by the presence at water’s interfaces a negatively charged solute free zone of several hundred microns in thickness called the exclusion zone (EZ). Further evidence was demonstrated by Ovchinnikova’s experiments (2009) showing that water can store and release substantial amount of charge. We demonstrate that the charge storage capacity of water arises from highly stable large-scale ionic structures with measurable charge imbalances and discrete levels of charge density. We also show evidence that the charge zones formation requires ionic solutes, and their formation correlate to large change in conductivity, by as much as 250%. Our experiments indicate that large-scale structuring plays a pivotal role in electrolysis and conductivity in ionic solution. We propose that water is an electrochemically active medium and present a new model of electrolysis and conductivity in ionic solution. Public Library of Science 2019-03-26 /pmc/articles/PMC6435176/ /pubmed/30913207 http://dx.doi.org/10.1371/journal.pone.0213697 Text en © 2019 Yee et al http://creativecommons.org/licenses/by/4.0/ This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
spellingShingle Research Article
Yee, Chut-Ngeow
Ooi, C. H. Raymond
Tan, Luck-Pheng
Misran, Misni
Tang, Nyiak-Tao
Large-scale structure formation in ionic solution and its role in electrolysis and conductivity
title Large-scale structure formation in ionic solution and its role in electrolysis and conductivity
title_full Large-scale structure formation in ionic solution and its role in electrolysis and conductivity
title_fullStr Large-scale structure formation in ionic solution and its role in electrolysis and conductivity
title_full_unstemmed Large-scale structure formation in ionic solution and its role in electrolysis and conductivity
title_short Large-scale structure formation in ionic solution and its role in electrolysis and conductivity
title_sort large-scale structure formation in ionic solution and its role in electrolysis and conductivity
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6435176/
https://www.ncbi.nlm.nih.gov/pubmed/30913207
http://dx.doi.org/10.1371/journal.pone.0213697
work_keys_str_mv AT yeechutngeow largescalestructureformationinionicsolutionanditsroleinelectrolysisandconductivity
AT ooichraymond largescalestructureformationinionicsolutionanditsroleinelectrolysisandconductivity
AT tanluckpheng largescalestructureformationinionicsolutionanditsroleinelectrolysisandconductivity
AT misranmisni largescalestructureformationinionicsolutionanditsroleinelectrolysisandconductivity
AT tangnyiaktao largescalestructureformationinionicsolutionanditsroleinelectrolysisandconductivity