Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests

Deracemization is a powerful method by which a racemic mixture can be transformed into an excess of one enantiomer with the aid of chiral auxiliaries, but has been applied only to small chiral molecular systems. Here we report a deracemization of a racemic double-stranded spiroborate helicate contai...

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Detalles Bibliográficos
Autores principales: Ousaka, Naoki, Yamamoto, Shinya, Iida, Hiroki, Iwata, Takuya, Ito, Shingo, Hijikata, Yuh, Irle, Stephan, Yashima, Eiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6441078/
https://www.ncbi.nlm.nih.gov/pubmed/30926811
http://dx.doi.org/10.1038/s41467-019-09443-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6441078/
https://www.ncbi.nlm.nih.gov/pubmed/30926811
http://dx.doi.org/10.1038/s41467-019-09443-z

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