Asymmetric Vinylogous Aldol-type Reactions of Aldehydes with Allyl Phosphonate and Sulfone

Two catalytic asymmetric vinylogous aldol-type reactions of aldehydes with allyl phosphonate and allyl sulfone have been uncovered in good to high yields for the first time. The bulky ligand—(R)-DTBM-SEGPHOS—was found to be the key to perfectly control both regio- and enantioselectivities. Transform...

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Detalles Bibliográficos
Autores principales: Yue, Wen-Jun, Zhang, Cheng-Yuan, Yin, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6443912/
https://www.ncbi.nlm.nih.gov/pubmed/30928697
http://dx.doi.org/10.1016/j.isci.2019.03.010

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6443912/
https://www.ncbi.nlm.nih.gov/pubmed/30928697
http://dx.doi.org/10.1016/j.isci.2019.03.010

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