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Hoveyda–Grubbs catalysts with an N→Ru coordinate bond in a six-membered ring. Synthesis of stable, industrially scalable, highly efficient ruthenium metathesis catalysts and 2-vinylbenzylamine ligands as their precursors

A novel and efficient approach to the synthesis of 2-vinylbenzylamines is reported. This involves obtaining 2-vinylbenzylamine ligands from tetrahydroisoquinoline by alkylation and reduction followed by the Hofmann cleavage. The resultant 2-vinylbenzylamines allowed us to obtain new Hoveyda–Grubbs c...

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Detalles Bibliográficos
Autores principales:	Polyanskii, Kirill B, Alekseeva, Kseniia A, Raspertov, Pavel V, Kumandin, Pavel A, Nikitina, Eugeniya V, Gurbanov, Atash V, Zubkov, Fedor Ivanovich
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2019
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6444410/ https://www.ncbi.nlm.nih.gov/pubmed/30992725 http://dx.doi.org/10.3762/bjoc.15.73

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