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Off-stoichiometry improves the photostructuring of thiol–enes through diffusion-induced monomer depletion
Thiol–enes are a group of alternating copolymers with highly ordered networks and are used in a wide range of applications. Here, “click” chemistry photostructuring in off-stoichiometric thiol–enes is shown to induce microscale polymeric compositional gradients due to species diffusion between non-i...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6444721/ https://www.ncbi.nlm.nih.gov/pubmed/31057810 http://dx.doi.org/10.1038/micronano.2015.43 |